Vibrational relaxation of CN stretch of pseudo-halide anions (OCN-, SCN-, and SeCN-) in polar solvents.

Abstract

The vibrational relaxation dynamics of pseudo-halide anions XCN- (X = O, S, Se) in polar solvents were studied to understand the effect of charge on solute-to-solvent intermolecular energy transfer (IET) and solvent assisted intramolecular vibrational relaxation (IVR) pathways. The T1 relaxation times of the CN stretch in these anions were measured by IR… (More)

Topics

Cite this paper

@article{Lenchenkov2006VibrationalRO, title={Vibrational relaxation of CN stretch of pseudo-halide anions (OCN-, SCN-, and SeCN-) in polar solvents.}, author={Victor Lenchenkov and Chunxing She and Tianquan Lian}, journal={The journal of physical chemistry. B}, year={2006}, volume={110 40}, pages={19990-7} }