Vibrational dynamics and structural relaxation in aqueous electrolyte solutions in the liquid, undercooled liquid and glassy states

@inproceedings{Dupuy1992VibrationalDA,
  title={Vibrational dynamics and structural relaxation in aqueous electrolyte solutions in the liquid, undercooled liquid and glassy states},
  author={Jean-Pierre Dupuy and J. F. Jal and Brigitte Pr{\'e}vel and A. Aouizerat-Elarby and Pierre Chieux and A. Jos{\'e} Dianoux and Jean Francois Legrand},
  year={1992}
}
In very concentrated aqueous electrolyte solutions, the competition between dipolar and ionic forces and most of the system properties, are finely monitored by the concentration. For LiCl, RH 2 O (R being the number of water moles per mole of salt) two domains of concentration exist around even hydration numbers R=6 and R=4, which can be reversibly undercooled from the liquid to the glassy state. At other concentrations, for R<12, metastability is achieved only in a restricted temperature range… CONTINUE READING

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