Vibrational coherence and energy transfer in two-dimensional spectra with the optimized mean-trajectory approximation.

Abstract

The optimized mean-trajectory (OMT) approximation is a semiclassical method for computing vibrational response functions from action-quantized classical trajectories connected by discrete transitions that represent radiation-matter interactions. Here, we extend the OMT to include additional vibrational coherence and energy transfer processes. This… (More)
DOI: 10.1063/1.4916644

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