Vesicular mixed gemini-SDS-hemin-imidazole complex as a peroxidase-like nano artificial enzyme.


A biomimetic was designed for the construction of a new efficient peroxidase-like nano artificial enzyme with a heme-imidazole component complexed with gemini 12-2-12/SDS supramolecules. The presence of a simple surfactant mixture (SDS/gemini 12-2-12 at a particular concentration) provided an apoprotein-like hydrophobic pocket for the heme-imidazole moiety… (More)
DOI: 10.1021/jp112051t


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