Vertex Group Effects in Entangled Polystyrene-Polyhedral Oligosilsesquioxane ( POSS ) Copolymers

@inproceedings{Wu2009VertexGE,
  title={Vertex Group Effects in Entangled Polystyrene-Polyhedral Oligosilsesquioxane ( POSS ) Copolymers},
  author={Jian Wu and Timothy S. Haddad and Patrick T Mather},
  year={2009}
}
The linear viscoelastic behavior of thermoplastic hybrid inorganic-organic polymers synthesized through radical copolymerization of styrene and styryl-based polyhedral oligosilsesquioxane (POSS), R7(Si8O12) (C6H4CHdCH2), with R ) isobutyl (iBu), cyclopentyl (Cp), and cyclohexyl (Cy), was studied to reveal a significant influence of the vertex group, R. The glass transition temperatures were found to feature a strong and complex POSS vertex group dependence, with iBu playing a plasticizer-like… CONTINUE READING
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