Versatile synthesis and enlargement of functionalized distorted heptagon-containing nanographenes† †Electronic supplementary information (ESI) available: General details, synthesis and spectroscopy data of new compounds and copies of 1H and 13C-NMR spectra of new compounds. Experimental details on optical and electrochemical measurements. Crystal data and structure refinement of compounds 2, 6a, 6d and 6h. Further details on theoretical calculations and Cartesian coordinates of computed structures. VT-1H-NMR, 2D-NMR and HRMS spectra of compounds 1 and 2. CCDC 1485682–1485685. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc02895k Click here for additional data file. Click here for additional data file.

a. Departamento Química Orgánica, Universidad de Granada (UGR). C. U. Fuentenueva,18071 Granada, Spain. email: araceligc@ugr.es, jmcuerva@ugr.es b. Departamento de Fisicoquímica, Facultad de Farmacia, UGR. Cartuja Campus, 18071 Granada, Spain. c. Departamento de Química Orgánica I, Universidad del País Vasco, E-20018, San Sebastián (Spain) d. Departamento… CONTINUE READING