Variable-angle synchronous fluorescence spectrometry and rank annihilation methods for mixture resolution.
@article{Snchez1996VariableangleSF, title={Variable-angle synchronous fluorescence spectrometry and rank annihilation methods for mixture resolution.}, author={F. Garc{\'i}a S{\'a}nchez and M. Cedazo and J. Lovillo and A. Navas D{\'i}az}, journal={Talanta}, year={1996}, volume={43 8}, pages={ 1327-33 } }
The potential of variable angle synchronous spectroscopy (VASS) for fluorescent mixtures resolution was assessed and compared with the rank annihilation method (RAM). For this purpose, a set of excitation-emission matrices from three standard cyclodextrin fluorescence-enhanced solutions of the pesticides aminocarb, carbendazim and coumatetralyl and a mixture of them was obtained. Careful selection of the spectral routes to be scanned provides analyte signals that are free of interferences… CONTINUE READING
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