Variable-angle synchronous fluorescence spectrometry and rank annihilation methods for mixture resolution.

  title={Variable-angle synchronous fluorescence spectrometry and rank annihilation methods for mixture resolution.},
  author={Francisco Garc{\'i}a S{\'a}nchez and M Cedazo and J. Lovillo and Aurora Navas D{\'i}az},
  volume={43 8},
The potential of variable angle synchronous spectroscopy (VASS) for fluorescent mixtures resolution was assessed and compared with the rank annihilation method (RAM). For this purpose, a set of excitation-emission matrices from three standard cyclodextrin fluorescence-enhanced solutions of the pesticides aminocarb, carbendazim and coumatetralyl and a mixture of them was obtained. Careful selection of the spectral routes to be scanned provides analyte signals that are free of interferences… 
16 Citations
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