Vanadocene complexes of amino acids containing secondary amino group: the first evidence of O,O-bonded carboxylic group to vanadocene(IV) moiety.

@article{Vinklrek2010VanadoceneCO,
  title={Vanadocene complexes of amino acids containing secondary amino group: the first evidence of O,O-bonded carboxylic group to vanadocene(IV) moiety.},
  author={Jarom{\'i}r Vinkl{\'a}rek and Tereza Dedourkov{\'a} and Jan Honz{\'i}{\vc}ek and A. M. Ruzicka},
  journal={Journal of inorganic biochemistry},
  year={2010},
  volume={104 9},
  pages={936-43}
}
Reaction of vanadocene dichlorides (Cp(2)VCl(2) and (eta(5)-C(5)H(4)Me)(2)VCl(2)) with amino acids containing secondary amino groups gives three types of complexes: a) compounds with N,O-bonded amino acid, b) O-bonded amino acids and c) O,O-bonded amino acid. The complexes with N,O-bonded amino acid and O-bonded amino acids were observed in the case of l… CONTINUE READING