VAPORIZATION BEHAVIOR OF CHROMIUM PHOSPHIDES. THE SOLID TWO‐PHASE REGIONS CRP‐CR12P7, CR12P7‐CR3P, AND CR3P‐CR

@inproceedings{Myers1985VAPORIZATIONBO,
  title={VAPORIZATION BEHAVIOR OF CHROMIUM PHOSPHIDES. THE SOLID TWO‐PHASE REGIONS CRP‐CR12P7, CR12P7‐CR3P, AND CR3P‐CR},
  author={Clifford E. Myers and Greg A. Kisacky and J. K. Klingert},
  year={1985}
}
Abstract : The vaporization reactions 24/5 CrP(s) = 2/5 Cr12P7(s) + P2(g) (1194-1479K), 2/3 Cr12P7(s) = 8/3 Cr3P(s) + P2(g) (1421-1541K), and 2 Cr3P(s) = 6Cr4(S) + P2(g) (1543-1768K) have been studied by mass-loss effusion in the temperature ranges indicated. The reactions are kinetically inhibited. Enthalpies of formation and atomization respectively were found. Cr P was found to follow the trend in atomization enthalpy to valence state atoms established in the series MnP, FeP, CoP, and NiP.