Using nitrogen isotope fractionation to assess the oxidation of substituted anilines by manganese oxide.

Abstract

We explored the N isotope fractionation associated with the oxidation of substituted primary aromatic amines, which are often the position of initial attack in transformation processes of environmental contaminants. Apparent (15)N-kinetic isotope effects, AKIE(N), were determined for the oxidation of various substituted anilines in suspensions of manganese… (More)
DOI: 10.1021/es200743t

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