Use of model Pt(111) single crystal electrodes under HMRDE configuration to study the redox mechanism for charge injection at aromatic/metal interfaces.


The electrochemical reactivity of hydroquinone-derived, catechol-derived and benzene-derived adlayers is compared at Pt(111) single-crystal surfaces (i) under stagnant hanging meniscus (HM) configuration and (ii) under hydrodynamic conditions imposed by combining the HM configuration with the rotating disk electrode (RDE) that merge in the so-called HMRDE… (More)
DOI: 10.1021/la902569z


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