Updated Abraham solvation parameters for polychlorinated biphenyls.

@article{Noort2010UpdatedAS,
  title={Updated Abraham solvation parameters for polychlorinated biphenyls.},
  author={Paul C M van Noort and Joris J. H. Haftka and John Robert Parsons},
  journal={Environmental science & technology},
  year={2010},
  volume={44 18},
  pages={7037-42}
}
This study shows that the recently published polychlorinated biphenyl (PCB) Abraham solvation parameters predict PCB air-n-hexadecane and n-octanol-water partition coefficients very poorly, especially for highly ortho-chlorinated congeners. Therefore, an updated set of PCB solvation parameters was derived from four PCB properties and associated Abraham solvation equations. Additionally, the influence of ortho-chlorination on PCB solvent accessible volume and surface area was investigated. The… CONTINUE READING

Citations

Publications citing this paper.
Showing 1-10 of 27 extracted citations

References

Publications referenced by this paper.
Showing 1-10 of 20 references

Henry ’ s law constants for eleven polychlorinated biphenyls at 20 ° C

Th. E. M. Ten Hulscher, H. van den Heuvel, P. C. M. van Noort, H. A. J. Govers
J . Chem . Eng . Data • 2006

Similar Papers

Loading similar papers…