Unveiling the Transient Template in the Self-Assembly of a Molecular Oxide Nanowheel

@article{Miras2010UnveilingTT,
  title={Unveiling the Transient Template in the Self-Assembly of a Molecular Oxide Nanowheel},
  author={Haralampos N. Miras and Geoffrey J T Cooper and De‐Liang Long and Hartmut Bögge and Achim M{\"u}ller and Carsten Streb and Leroy Cronin},
  journal={Science},
  year={2010},
  volume={327},
  pages={72 - 74}
}
A Hidden Template The entropic challenge inherent in forming a ring-shaped molecule generally increases considerably with the size of the ring. Assuming that a linear precursor must bind its ends together, extending its length diminishes the likelihood of the opposite ends approaching one another. In the absence of an external force, how then can a family of molybdenum oxide rings, several nanometers in diameter (quite large at the molecular scale), self-assemble? Miras et al. (p. 72, see the… 

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