Unraveling the synthesis of homoleptic [Ag(N,N-diaryl-NHC)2]Y (Y = BF4, PF6) complexes by ball-milling.

@article{Beillard2016UnravelingTS,
  title={Unraveling the synthesis of homoleptic [Ag(N,N-diaryl-NHC)2]Y (Y = BF4, PF6) complexes by ball-milling.},
  author={Audrey Beillard and Xavier Bantreil and Thomas-Xavier M{\'e}tro and Jean Martinez and Fr{\'e}d{\'e}ric Lamaty},
  journal={Dalton transactions},
  year={2016},
  volume={45 44},
  pages={17859-17866}
}
A user-friendly and general mechanochemical method was developed to access rarely described NHC (N-heterocyclic carbene) silver(i) complexes featuring N,N-diarylimidazol(idin)ene ligands and non-coordinating tetrafluoroborate or hexafluorophosphate counter anions. Comparison with syntheses in solution clearly demonstrated the superiority of the ball-milling conditions. 
Recent Discussions
This paper has been referenced on Twitter 9 times over the past 90 days. VIEW TWEETS

From This Paper

Topics from this paper.
1 Citations
0 References
Similar Papers

Similar Papers

Loading similar papers…