Unprecedented side reactions in Stille coupling: desired ones for Stille polycondensation.

Abstract

Two types of unprecedented side reactions were identified in the Stille coupling reaction, including the direct C-H stannylation of the α-hydrogen of thiophene and the stannylation of arylbromides with trialkylstannane bromide. These results reveal the major source of enhancements for Stille polycondensation efficiency. 
DOI: 10.1039/c5cc05404d

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Cite this paper

@article{Huang2015UnprecedentedSR, title={Unprecedented side reactions in Stille coupling: desired ones for Stille polycondensation.}, author={Hongyan Huang and Guanyuan Jiao and Shuli Liu and Quan Li and Xin Shi and Nina Fu and Lianhui Wang and Baomin Zhao and Wei Huang}, journal={Chemical communications}, year={2015}, volume={51 87}, pages={15846-9} }