Unimolecular dissociation of anions derived from succinic acid (H2Su) in the gas phase: HSu- and ClMgSu-. Relationship to CO2 fixation.

Abstract

Electrospray ionization of mixtures of succinic acid (here denoted H2Su) and magnesium chloride in water/methanol give rise to ions of the type ESu- (E = H or ClMg). The unimolecular dissociation of these ions was studied by collisionally induced dissociation mass spectrometry and interpreted by quantum chemical calculations (density functional theory and… (More)
DOI: 10.1177/1469066717729904

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