Unified equation for access to rate constants of first-order reactions in dynamic and on-column reaction chromatography.

@article{Trapp2006UnifiedEF,
  title={Unified equation for access to rate constants of first-order reactions in dynamic and on-column reaction chromatography.},
  author={Oliver Trapp},
  journal={Analytical chemistry},
  year={2006},
  volume={78 1},
  pages={
          189-98
        }
}
A unified equation to evaluate elution profiles of reversible as well as irreversible (pseudo-) first-order reactions in dynamic chromatography and on-column reaction chromatography has been derived. Rate constants k1 and k(-1) and Gibbs activation energies are directly obtained from the chromatographic parameters (retention times tR(A) and tR(B) of the interconverting or reacting species A and B, the peak widths at half-height wA and wB, and the relative plateau height h(p)), the initial… CONTINUE READING

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