Ultrasound-assisted oxidative cleavage of acetylenic and ethylenic bonds in unsaturated fatty esters with potassium permanganate

@article{LieKenJie2007UltrasoundassistedOC,
  title={Ultrasound-assisted oxidative cleavage of acetylenic and ethylenic bonds in unsaturated fatty esters with potassium permanganate},
  author={Marcel S. F. Lie Ken Jie and Prabhavathi Kalluri},
  journal={Lipids},
  year={2007},
  volume={31},
  pages={1299-1301}
}
The effect of ultrasound on the oxidation of unsaturated fatty esters was investigated. Unsaturated fatty esters containing acetylenic or olefinic bonds or both were oxidatively cleaved with KMnO4 in aqueous acetic acid (AcOH/H2O, 1:1, vol/vol for olefinic fatty esters and AcOH/H2O, 9:1, vol/vol for acetylenic fatty esters) to yield the corresponding carboxylic acid moieties in quantitative yields, when the reactions were conducted under ultrasound (20 kHz, 53 W/cm2, 8–15 min). The methyl ester… 

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