UV spectroscopic studies and charge transfer properties of azobenzene-containing cyclopentadienyliron complexes of arenes: a combined experimental and density functional theoretical study.


This study investigates the UV-Vis absorption and fluorescence emission of newly synthesized (η(6)-4-(4-nitrophenylazo) phenoxyl benzene) (η(5)-cyclopentadienyl) iron hexafluorophosphate (Fc-azo). Quantum chemical calculations of the orbital energy, geometrical structure, absorption spectra, and first hyperpolarizability (β) values of the Fc-azo were… (More)
DOI: 10.1016/j.saa.2012.11.062


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