Two organic-inorganic hybrid 3D {P(5)W(30)}-based heteropolyoxotungstates with transition-metal/Ln-carboxylate-Ln connectors.

Abstract

Two unique organic-inorganic hybrid polyoxometalates constructed from Preyssler-type [Na(H2 O)P5 W30 O110 ](14-) ({P5 W30 }) subunits and TM/Ln-carboxylate-Ln connectors (TM=transition metal, Ln=lanthanide), KNa7 [{Sm6 Mn(μ-H2 O)2 (OCH2 COO)7 (H2 O)18 }{Na(H2 O)P5 W30 O110 }]⋅22 H2 O (1) and K4 [{Sm4 Cu2 (gly)2 (ox)(H2 O)24 }{NaP5 W30 O110 }]Cl2 ⋅25 H2 O (2… (More)
DOI: 10.1002/asia.201301305

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Cite this paper

@article{Li2014TwoOH, title={Two organic-inorganic hybrid 3D \{P(5)W(30)\}-based heteropolyoxotungstates with transition-metal/Ln-carboxylate-Ln connectors.}, author={Yan-Ying Li and Junwei Zhao and Qi Wei and Bai-Feng Yang and Huan He and Guo-Yu Yang}, journal={Chemistry, an Asian journal}, year={2014}, volume={9 3}, pages={858-67} }