Two highly-connected, chiral, porous coordination polymers featuring novel heptanuclear metal carboxylate clusters.

@article{Hou2008TwoHC,
  title={Two highly-connected, chiral, porous coordination polymers featuring novel heptanuclear metal carboxylate clusters.},
  author={Lei Hou and Jie‐Peng Zhang and Xiao‐Ming Chen and Seik Weng Ng,},
  journal={Chemical communications},
  year={2008},
  volume={34},
  pages={
          4019-21
        }
}
Two novel (3,12)-connected, chiral porous coordination polymers featuring 3D intersecting pore structures, selective sorption and solvothermal resistance properties are constructed by linking 3-connected benzene-1,3,5-tribenzoic acid with two types of 12-connected heptanuclear metal carboxylate clusters. 
80 Citations

Figures from this paper

A metal–organic framework with coordinatively unsaturated metal centers and microporous structure
A novel two dimensional porous framework [Cd3(BTB)2(DEF)4]n·2nDEF (1) based on {Cd3} building blocks with bilayer honeycomb structure constructed from cadmium ion bridged honeycomb layers exhibits
An eight-connected porous metal–organic framework based on hetero pentanuclear clusters
A new MOF based on hetero pentanuclear clusters, [(CH3)2NH2]1.66[Cd1.84Na0.66(BDC)3]·DMF·0.5EtOH (1), has been prepared. Iodine adsorption studies reveal that 1 can reversibly adsorb iodine.
An unprecedented (4,10)-connected porous metal–organic framework containing two rare large secondary building units (SBUs)
A three-dimensional tetrazole-based Cd(II) metal–organic framework containing rare large Cd8 and Cd23 secondary building units has been hydrothermally prepared through in situ metal/ligand reaction,
An octacobalt cluster based, (3,12)-connected, magnetic, porous coordination polymer.
Solvothermal reaction of CoSO(4) with 2,6-di-p-carboxyphenyl-4,4'-bipyridine affords a novel, octacobalt cluster based, (3,12)-connected porous framework, which exhibits gas sorption and spin-glassy
A porous metal-organic framework based on Zn6O2 clusters: chemical stability, gas adsorption properties and solvatochromic behavior.
TLDR
The obtained Zn-MOF shows solvatochromic behavior for fluorescence sensing of small molecules, gas adsorption properties and exceptional chemical stability and might have applications for separation and detection purposes.
A 9-connected metal–organic framework with gas adsorption properties
A 9-connected, trinuclear cluster-based microporous metal–organic framework, Ni3(OH)(Ina)3(BDC)1.5 (Ina = isonicotinate and BDC = 1,4-benzenedicarboxylate) (1), was synthesized and characterized. The
New chiral coordination polymers constructed from well elaborated achiral and chiral ligands
The elaboration of structurally related tetrazolate-based ligands from achiral to chiral led to the formation of two new chiral coordination polymers (CCPs). Compound 1 contains an infinite 1D zigzag
...
1
2
3
4
5
...

References

SHOWING 1-10 OF 28 REFERENCES
A twelve-connected Cu6S4 cluster-based coordination polymer.
TLDR
A metal-organic framework [Cu3(4-pyridinethiolate)2(CN)] which has twelve-connected face-centered cubic topology with Cu6S4 clusters as nodes.
A novel metal-organic framework with the diamondoid topology constructed from pentanuclear zinc-carboxylate clusters
A new 3D MOF, [Zn5(μ3-O)2(bpdc)4(DMF)2(EtOH)2]·3(DMF)·3(EtOH)·5(H2O) (1) (bpdc = 4,4‘-biphenyldicarboxylate, DMF = N,N-dimethylformamide and EtOH = ethanol), has been synthesized under mild
Stability and porosity enhancement through concurrent ligand extension and secondary building unit stabilization.
A trigonal nanosized carboxylate ligand, 1,3,5-tris[4'-carboxy(1,1'-biphenyl-4-yl)]benzene (TCBPB), has been synthesized and applied in the construction of porous metal-organic frameworks (MOFs). A
Microporous metal-organic framework constructed from heptanuclear zinc carboxylate secondary building units.
A novel, three-dimensional, noninterpenetrating microporous metal-organic framework (MOF), [Zn7O2(pda)5(H2O)2]5 DMF4 EtOH 6 H2O (1) (H2PDA=p-phenylenediacrylic acid, DMF=N,N-dimethylformamide,
Probing the Lewis acid sites and CO catalytic oxidation activity of the porous metal-organic polymer [Cu(5-methylisophthalate)].
A new metal−organic polymer material exhibits the excellent and stable CO oxidation catalytic activity. Its open Lewis acid sites on the channel walls were probed by CO adsorption.
Twelve-connected porous metal-organic frameworks with high H(2) adsorption.
TLDR
The twelve-connected metal-organic frameworks [LH(2) = pyridine-3,5-bis(phenyl-4-carboxylic acid)] have been prepared and characterised and can be desolvated to form porous materials that show adsorption up to 4.15 wt% at 77 K.
Immobilization of sodium ions on the pore surface of a porous coordination polymer.
A porous coordination polymer (PCP) with immobilization of sodium cations on the pore surface has been synthesized, by employing a bifunctional carboxylate/sulfonate ligand, and structurally
A dynamic porous magnet exhibiting reversible guest-induced magnetic behavior modulation
A flexible 3D porous magnet [KCo(7)(OH)(3)(ip)(6)(H(2)O)(4)]center dot 12H(2)O based on unprecedented trigonal-prismatic heptanuclear Co(II) clusters (see figure) is reported to undergo a reversible
Synthesis, characterization, and photoluminescence of isostructural Mn, Co, and Zn MOFs having a diamondoid structure with large tetrahedral cages and high thermal stability.
Three novel Mn, Co, and Zn MOFs containing large tetrahedral cages have been prepared and are stable up to 400 degree C; X-ray diffraction revealed the frameworks are isostructural having a
A Porous and Interpenetrated Metal–Organic Framework Comprising Tetranuclear IronIII–Oxo Clusters and Tripodal Organic Carboxylates and Its Implications for (3,8)-Coordinated Networks
A porous metal–organic framework (MOF), Fe4(μ3-O)2(BTB)8/3(DMF)2(H2O)2·(DMF)10(H2O)2 (1) (BTB = benzene-1,3,5-tribenzoate, DMF = N,N-dimethylformamide) has two interpenetrating 3D frameworks composed
...
1
2
3
...