Two-dimensional oxygen-17-vanadium-51 heteronuclear shift correlation NMR spectroscopy of the 17O-enriched inclusion complex [CH3CN.cntnd.(V12O324-)]. Relationship of cross-peak intensity to bond order

@inproceedings{Wagner1991TwodimensionalOH,
  title={Two-dimensional oxygen-17-vanadium-51 heteronuclear shift correlation NMR spectroscopy of the 17O-enriched inclusion complex [CH3CN.cntnd.(V12O324-)]. Relationship of cross-peak intensity to bond order},
  author={George W. Wagner},
  year={1991}
}
Two-dimensional NMR experiments for determination of molecular structure in solutions are not necessarily limited to only spin 1/2 nuclei in organic systems, and the method has been applied to half-integer quadrupolar nuclei (I>1/2) in order to characterize the structure of inorganic clusters in solution. The work reported herein demonstrates that heteronuclear shift correlation spectroscopy (HETCOR) is feasible for half-integer quadrupolar nuclei by applying the technique to {sup 17}O-enriched… CONTINUE READING