Two WV-MnIII bimetallic assemblies built by octacyanotungstate(v) and MnIII Schiff bases: molecular structures and a spin-flop transition.

@article{Ko2007TwoWB,
  title={Two WV-MnIII bimetallic assemblies built by octacyanotungstate(v) and MnIII Schiff bases: molecular structures and a spin-flop transition.},
  author={Hyun Hee Ko and Jeong Hak Lim and Houng Sik Yoo and Jun Sung Kang and Hyoung Chan Kim and Eui Kwan Koh and Chang Seop Hong},
  journal={Dalton transactions},
  year={2007},
  volume={20},
  pages={2070-6}
}
Two W(V)-Mn(III) bimetallic compounds, [Mn(Cl-salmen)(H(2)O)2]{[Mn(5-Clsalmen)(H(2)O)]2[W(CN)8].2H(2)O (1.2H(2)O) [5-Clsalmen = N,N'-(1-methylethylene)bis(5-chlorosalicylideneiminato) dianion], which contains trinuclear Mn(2)W and isolated Mn(III) moieties, and [Mn(3-MeOsalcy)(H(2)O)2]3[W(CN)(8)].2H(2)O (2.2H(2)O) [3-MeOsalcy = N,N'-(trans-1,2-cyclohexanediylethylene)bis(3-methoxysalicylideneiminato) dianion] molecules were prepared in redox processes and characterized using X-ray analysis and… CONTINUE READING