Two-Level Adaptive Training Branch Prediction

  title={Two-Level Adaptive Training Branch Prediction},
  author={Tse-Yu Yeh and Yale N. Patt},
  journal={Journal of the American Chemical Society},
  volume={135 32},
Many nickel-based catalysts have been reported for cross-coupling reactions of nonactivated alkyl halides. The mechanistic understanding of these reactions is still primitive. Here we report a mechanistic study of alkyl-alkyl Kumada coupling catalyzed by a preformed nickel(II) pincer complex ([(N2N)Ni-Cl]). The coupling proceeds through a radical process, involving two nickel centers for the oxidative addition of alkyl halide. The catalysis is second-order in Grignard reagent, first-order in… CONTINUE READING
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