Trivalent metal ions promote the malic enzyme-catalyzed building of carbon–carbon bonds from CO2and pyruvate

@article{Katagiri2020TrivalentMI,
  title={Trivalent metal ions promote the malic enzyme-catalyzed building of carbon–carbon bonds from CO2and pyruvate},
  author={Takayuki Katagiri and Yutaka Amao},
  journal={New Journal of Chemistry},
  year={2020},
  volume={44},
  pages={17208-17214}
}
Malic enzyme (ME) from chicken liver (EC 1.1.1.40) is an enzyme that catalyzes the decarboxylation of malate into pyruvate and CO2 and the reverse reaction that introduces CO2 as a carboxy-group to pyruvate to form malate via oxaloacetate in the presence of natural co-enzyme NADP+/NADPH. Thus, ME is an attractive biocatalyst for building carbon–carbon bonds through the carboxylation of pyruvate with CO2. Since ME mainly catalyzes the decarboxylation of malate to produce pyruvate via… Expand
1 Citations
Visible-light driven redox system of water-soluble zinc porphyrin and platinum nanoparticles for selective reduction of pyruvate to lactate
Lactate has received a great deal of attention as a raw material for biodegradable plastics. Lactate is synthesized by fermentation and chemical procedures. Using chemical procedures, lactate isExpand

References

SHOWING 1-10 OF 63 REFERENCES
Double-Electron Reduced Diphenylviologen as a Coenzyme for Biocatalytic Building Carbon–Carbon Bonds from CO2 as a Carbon Feedstock
Malate dehydrogenase (oxaloacetate-decarboxylating) commonly named malic enzyme (ME) from chicken liver (EC 1.1.1.40) catalyzes a reaction introducing CO2 as a carboxy-group to pyruvate to formExpand
Development of a dye molecule-biocatalyst hybrid system with visible-light induced carbon-carbon bond formation from CO2 as a feedstock.
TLDR
A visible light-induced photoredox system for carbon-carbon bond formation from CO2 with ME using 1,1'-diphenyl-4,4'-bipyridinium salt derivatives as a novel electron mediator with water-soluble tetraphenylporphyrin tetrasulfonate in the presence of triethanolamine as an electron donor was developed. Expand
Photochemical fixation of carbon dioxide: enzymic photosynthesis of malic, aspartic, isocitric, and formic acids in artificial media
Photosensitized regeneration of 1,4-dihydronicotinamide adenine dinucleotide phosphate (NADPH) with an artificial photosystem allows the enzymic fixation of CO2 through carboxylation of α-oxo acidsExpand
Visible light-induced reduction properties of diphenylviologen with water-soluble porphyrin
Abstract Molecular conversion reaction system containing a dye and a biocatalyst catalyzing a reaction of a carbon–carbon bond formation from CO2 as a feedstock were constructed. For example,Expand
Photochemical and Enzymatic Synthesis of Malic Acid from Pyruvic Acid and HCO3- with Combination System of Zinc Chlorin-e6 and Malic Enzyme in Aqueous Medium
Photochemical and enzymatic synthesis of malic acid from pyruvic acid and HCO3- was studied with malic enzyme (ME) and NADP+ photoreduction with ferredoxin-NADP+-reductase (FNR) by visible lightExpand
Photocatalytic conversion of lactic acid to malic acid through pyruvic acid in the presence of malic enzyme and semiconductor photocatalysts
The photocatalytic fixation of CO2 in pyruvic acid to yield malic acid has been achieved in TiO2 microcrystal and CdS particle suspensions using malic enzyme as the catalyst, methyl viologen as theExpand
Visible light-induced reduction system of diphenylviologen derivative with water-soluble porphyrin for biocatalytic carbon–carbon bond formation from CO2
Abstract From the view point of green chemistry, CO2 utilization technologies with solar energy including the photoredox system have been received a lot of attention. As one of them, photoredoxExpand
Photochemical and enzymatic methanol synthesis from HCO3− by dehydrogenases using water-soluble zinc porphyrin in aqueous media
Abstract We studied the photochemical and enzymatic synthesis of methanol from HCO3− using formate dehydrogenase (FDH) isolated from Candida boidinii, aldehyde dehydrogenase (AldDH) and alcoholExpand
Effect of chemical structure of bipyridinium salts as electron carrier on the visible-light induced conversion of CO2 to formic acid with the system consisting of water-soluble zinc porphyrin and formate dehydrogenase
Effect of chemical structures of some 2,2′-bipyridinium salts (BP2+) as the electron carrier molecules on the visible-light induced conversion of CO2 to formic acid with the system consisting ofExpand
Tethering of nicotinamide adenine dinucleotide inside hollow nanofibers for high-yield synthesis of methanol from carbon dioxide catalyzed by coencapsulated multienzymes.
TLDR
It is shown that cationic polyelectrolyte-doped hollow nanofibers provide an ideal scaffold for assembly of cofactor and multienzymes capable of synthesizing methanol from CO2 through a cascade multistep reaction involving cofactor regeneration. Expand
...
1
2
3
4
5
...