Trinuclear nickel and cobalt complexes containing unsymmetrical tripodal tetradentate ligands: syntheses, structural, magnetic, and catalytic properties.


The coordination chemistries of the tetradentate N2O2-type ligands N-(2-pyridylmethyl)iminodiethanol (H2pmide) and N-(2-pyridylmethyl)iminodiisopropanol (H2pmidip) have been investigated with nickel(ii) and cobalt(ii/iii) ions. Three novel complexes prepared and characterized are [(Hpmide)2Ni3(CH3COO)4] (1), [(Hpmide)2Co3(CH3COO)4] (2), and [(pmidip)2Co3… (More)
DOI: 10.1039/c6dt02701f


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