Tridymite-like host clathrate [K(H2O)n][CuZn(CN)4]: crystal structure, guest molecular motion and properties.

Abstract

A new clathrate [K(H(2)O)(n)][CuZn(CN)(4)] has been synthesized and its host structure has been determined by the single-crystal X-ray diffraction method. It has a [CuZn(CN)(4)](-) tridymite-like 3D framework host, formed with tetrahedral Cu(I) and Zn(II) ions and cyanide bridges and includes water molecules as guests, together with K(+). This tridymite… (More)
DOI: 10.1039/c0dt01201g

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Cite this paper

@article{Dan2011TridymitelikeHC, title={Tridymite-like host clathrate [K(H2O)n][CuZn(CN)4]: crystal structure, guest molecular motion and properties.}, author={Hiroki Dan and Shin-ichi Nishikiori and Osamu Yamamuro}, journal={Dalton transactions}, year={2011}, volume={40 5}, pages={1168-74} }