• DOI:10.1149/1.1856988
Corpus ID: 53997725

Trends in the exchange current for hydrogen evolution

@article{Nrskov2005TrendsIT,
  title={Trends in the exchange current for hydrogen evolution},
  author={J. N{\o}rskov and T. Bligaard and {\'A}. Logad{\'o}ttir and J. Kitchin and J. G. Chen and S. Pandelov and U. Stimming},
  journal={Journal of The Electrochemical Society},
  year={2005},
  volume={152}
}

• J. Nørskov, T. Bligaard, +4 authors U. Stimming
• Published 2005
• Physics
• Journal of The Electrochemical Society

Department of Physics, Technical University Munich, D-85748 Garching, GermanyA density functional theory database of hydrogen chemisorption energies on close packed surfaces of a number of transition andnoble metals is presented. The bond energies are used to understand the trends in the exchange current for hydrogen evolution. Avolcano curve is obtained when measured exchange currents are plotted as a function of the calculated hydrogen adsorptionenergies and a simple kinetic model is… Expand

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