Trends in ground-state entropies for transition metal based hydrogen atom transfer reactions.

@article{Mader2009TrendsIG,
  title={Trends in ground-state entropies for transition metal based hydrogen atom transfer reactions.},
  author={Elizabeth A. Mader and V. Manner and Todd F Markle and Adam Wu and J. A. Franz and J. M. Mayer},
  journal={Journal of the American Chemical Society},
  year={2009},
  volume={131 12},
  pages={
          4335-45
        }
}
Reported herein are thermochemical studies of hydrogen atom transfer (HAT) reactions involving transition metal H-atom donors M(II)LH and oxyl radicals. [Fe(II)(H(2)bip)(3)](2+), [Fe(II)(H(2)bim)(3)](2+), [Co(II)(H(2)bim)(3)](2+), and Ru(II)(acac)(2)(py-imH) [H(2)bip = 2,2'-bi-1,4,5,6-tetrahydropyrimidine, H(2)bim = 2,2'-bi-imidazoline, acac = 2,4-pentandionato, py-imH = 2-(2'-pyridyl)imidazole)] each react with TEMPO (2,2,6,6-tetramethyl-1-piperidinoxyl) or (t)Bu(3)PhO(*) (2,4,6-tri-tert… Expand
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