Transition to the Most Probable Kinetic State in a Pre-steady State System Where K » K (a + C)

Abstract

A system containing a pre-steady state standard (non-autocatalytic) reaction, with multiple paths, evolves toward a kinetic state with the minimum attainable activation free energy. Displacement of the path frequency distribution in this transition was shown to minimise the affinity linked to this change in activation free energy. In damping this scalar… (More)

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