Transition state spectroscopy of the photoinduced Ca + CH(3)F reaction. 1. A cluster isolated chemical reaction study.

Abstract

The "cluster isolated chemical reactions" technique is used to examine the dynamics of the photoinduced reaction producing electronically excited CaF when 1:1 Ca-CH(3)F complexes are deposited at the surface of large argon clusters. This technique ensures quantitatively that 1:1 complexes are actually at the origin of the observed signals. The reaction is… (More)

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@article{Gaveau2005TransitionSS, title={Transition state spectroscopy of the photoinduced Ca + CH(3)F reaction. 1. A cluster isolated chemical reaction study.}, author={M-A Gaveau and Eric Gloaguen and P Fournier and J-M Mestdagh}, journal={The journal of physical chemistry. A}, year={2005}, volume={109 42}, pages={9494-8} }