Transition metal complexes with thiosemicarbazide-based ligands. XV. A square-pyramidal NiII complex with an asymmetric coordination of 2, 6-diacetylpyridine bis(S-methylisothiosemicarbazone)

Abstract

The title compound, [diacetylpyridine bis(S-methylisothiosemicarbazonato)]iodonickel(II), [Ni(C(13)H(18)N(7)S(2))I], is the first example of a complex involving the (2)N coordination of the isothiosemicarbazide moiety. 2,6-Diacetylpyridine bis(S-methylisothiosemicarbazone), as a potentially pentadentate ligand (N(5)), is coordinated as a tetradentate… (More)

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@article{Leovac2000TransitionMC, title={Transition metal complexes with thiosemicarbazide-based ligands. XV. A square-pyramidal NiII complex with an asymmetric coordination of 2, 6-diacetylpyridine bis(S-methylisothiosemicarbazone)}, author={Leovac and Bogdanovic and Cesljevic and Divjakovic}, journal={Acta crystallographica. Section C, Crystal structure communications}, year={2000}, volume={56 (Pt 8)}, pages={936-8} }