Transition-metal-catalyzed reactions of allenes

@article{Ma2006TransitionmetalcatalyzedRO,
  title={Transition-metal-catalyzed reactions of allenes},
  author={Shengming Ma},
  journal={Pure and Applied Chemistry},
  year={2006},
  volume={78},
  pages={197 - 208}
}
  • Shengming Ma
  • Published 2006
  • Chemistry
  • Pure and Applied Chemistry
Pathways for carbometallation of simple allenes and allenes bearing a nucleophilic functionality with RMX have been discussed. The bisallene approaches for the efficient synthesis of carbocycles and heterocycles have been developed. 
Palladium-catalyzed asymmetric coupling cyclization of terminal γ-allenols with aryl iodides.
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Abstract Progresses in the field of intramolecular additions of nitrogen nucleophiles to allenes and domino reactions involving intramolecular C–N bond formation are reviewed under catalysis withExpand
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A new and efficient Pd(II) -catalyzed intermolecular annulation of N-benzoylsulfonamide with allenes for the synthesis of 3,4-dihydroisoquinolin-1(2H)-ones is reported. This CH functionalization isExpand
An expedient stereoselective route to the ACE tricyclic core of manzamine A via a palladium-catalysed arylative allene spirocyclisation cascade
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Regio- and Stereoselective Reductive Cyclization of 1,5-Bisallenes under Hydrogenation Conditions
E-mail: hyjang2@ajou.ac.krReceived January 10, 2011, Accepted February 11, 2011Key Words : Hydrogenative cyclization, Bisallene, Hydrometallation, Platinum hydrideThe transition metal-catalyzedExpand
Key Factors for High Diastereo- and Enantioselectivity of Umpolung Cyclizations of Aldehyde-Containing Allylpalladium Intermediates
Two palladium/chiral diphosphine-catalyzed umpolung cyclizations of aldehyde-containing allylic acetates and allenes with arylboronic acid are fully investigated to establish key factors in their h...
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