Transition Metal Complexes of Diazenes, XVII [1] Reactions of 1,2-Diazetines and 1,2-Diazetine-N-oxides with Iron Carbonyls

Abstract

Max-Planck-Institut für Kohlenforschung, D-4330 Mülheim a. d. Ruhr Z. Naturforsch. 37 b, 463-467 (1982); received November 13, 1981 I,2-Diazetines, 1,2-Diazetine-N-oxide, Iron Complexes, X-ray Enneacarbonyldiiron reacts with 3,3,4,4-tetramethyl-l,2-diazetine (L) or its mono-Noxide (L') to form complexes (L)Fe(CO)4 (3), (L)Fe2(CO)7 (4), (L)Fe2(CO)6 (5), or (L')Fe(CO)4 (6), and small amounts of deoxygenated 4 and 5, respectively. Formation and stability of the complexes is compared with those of ligands with smaller and larger ring sizes and discussed in terms of the electronic properties of the ligand lone-pair Orbitals. The molecular structure of 4 is established by X-ray analysis.

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Cite this paper

@inproceedings{Albini2012TransitionMC, title={Transition Metal Complexes of Diazenes, XVII [1] Reactions of 1,2-Diazetines and 1,2-Diazetine-N-oxides with Iron Carbonyls}, author={Angelo Albini and Horst Kisch and A K I Chiang}, year={2012} }