Trans-diaryl epoxides: asymmetric synthesis, ring-opening, and absolute configuration.

Abstract

Anthryl-phenyl, phenanthryl-phenyl, and naphthyl-phenyl trans-epoxides (1, 2, and 3, respectively) having enantiomeric purities of 95%, 99%, and 96% were synthesized from a diastereo and enantiopure sulfonium salt derived from Eliel's oxathiane. The determination of their (1R,2R) absolute configurations was achieved by application of the CD exciton… (More)

Topics

Figures and Tables

Sorry, we couldn't extract any figures or tables for this paper.