Trace analysis of airborne 1,6-hexamethylenediisocyanate and the related aminoisocyanate and diamine by glass capillary gas chromatography.

@article{Skarping1988TraceAO,
  title={Trace analysis of airborne 1,6-hexamethylenediisocyanate and the related aminoisocyanate and diamine by glass capillary gas chromatography.},
  author={G. Skarping and M. Dalene and L. Mathiasson},
  journal={Journal of chromatography},
  year={1988},
  volume={435 3},
  pages={
          453-68
        }
}
  • G. Skarping, M. Dalene, L. Mathiasson
  • Published 1988
  • Chemistry, Medicine
  • Journal of chromatography
    • A capillary gas chromatographic method was developed for the analysis of complex air mixtures of 1,6-hexamethylenediisocyanate, 1,6-hexamethyleneaminoisocyanate and 1,6-hexamethylenediamine. The method is based on derivatization in the sampling step of the reactive isocyanate groups to corresponding urethane groups by the alkaline ethanolic solvent and a subsequent derivatization of remaining amino groups to amide groups with heptafluorobutyric acid anhydride. The overall procedure, including… CONTINUE READING
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    24 Citations
    Background Citations
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    Methods Citations
    1
    24 Citations
    Citation Type

    Citation Type

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    Biological monitoring of isocyanates and related amines
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    Evaluation of Chromatographic Methods for the Determination of Isocyanates in Air
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    Chromatographic determination of amines in biological fluids with special reference to the biological monitoring of isocyanates and amines. IV. Determination of 1,6-hexamethylenediamine in human urine using capillary gas chromatography and selective ion monitoring.
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    Determination of isocyanates, aminoisocyanates and amines in air formed during the thermal degradation of polyurethane.
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    Biological monitoring of isocyanates and related amines
    • 30
    Chromatographic determination of amines in biological fluids with special reference to the biological monitoring of isocyanates and amines : I. Determination of 1,6-hexamethylenediamine using glass capillary gas chromatography and thermionic specific detection
    • 34
    Analysis of organic isocyanates using capillary supercritical-fluid chromatography
    • 9
    Determination of airborne isocyanates
    • 23
    Indirect determination of isocyanates by gas chromatography.
    • 6

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