Touching the upper limit for ferromagnetic interactions in hetero-bridged dinuclear [Cu2(II)] complexes using a novel N5-dinucleating ligand bearing an endogenous monoatomic amido(R-NH(-))-bridging group.

Abstract

A novel N(5)-dinucleating ligand 4-amino-3,5-bis(bipyridine-2-yl)-1,2,4-triazole allows the preparation for the first time, and under mild conditions, of single and mixed amido(R-NH(-))-bridged copper(II) complexes, the latter exhibiting very strong ferromagnetic coupling.

DOI: 10.1039/c1cc16590a

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Cite this paper

@article{Colacio2012TouchingTU, title={Touching the upper limit for ferromagnetic interactions in hetero-bridged dinuclear [Cu2(II)] complexes using a novel N5-dinucleating ligand bearing an endogenous monoatomic amido(R-NH(-))-bridging group.}, author={Enrique Colacio and Jesus E Perea-Buceta and Ant{\^o}nio Mota and Euan K Brechin and Alessandro Prescimone and Mikko M. H{\"a}nninen and Petri Sepp{\"a}l{\"a} and Rosario N{\'u}{\~n}ez}, journal={Chemical communications}, year={2012}, volume={48 6}, pages={805-7} }