Total synthesis of the proposed structure of a polyketide from Phialomyces macrosporus.

@article{Abe2015TotalSO,
  title={Total synthesis of the proposed structure of a polyketide from Phialomyces macrosporus.},
  author={H. Abe and Satoko Itaya and Kei Sasaki and Toyoharu Kobayashi and H. Ito},
  journal={Chemical communications},
  year={2015},
  volume={51 17},
  pages={
          3586-9
        }
}
Total synthesis of the proposed structure of a polyketide isolated from Phialomyces macrosporus is described. The synthesis involved chemoselective epoxidation, regioselective epoxide ring opening, chemo- and diastereoselective dihydroxylation, and vinylation of lactone accompanied by the formation of a furan ring. 
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