Total synthesis of (′)-ceratopicanol

@article{Mukai2002TotalSO,
  title={Total synthesis of (′)-ceratopicanol},
  author={C. Mukai and Minoru Kobayashi and I. J. Kim and M. Hanaoka},
  journal={Tetrahedron},
  year={2002},
  volume={58},
  pages={5225-5230}
}
Abstract Total synthesis of (±)-ceratopicanol ( 1 ) from commercially available 2-allyl-2-methylcyclopenta-1,3-dione ( 6 ) was completed. By taking advantage of the two carbonyl functionalities, 6 was transformed into the enyne 14 having an alkyne moiety, methyl substituent, and the hydroxy functionality with proper stereochemistry. The Pauson–Khand reaction of 14 was followed by chemical modifications resulting in the alternative total synthesis of (±)-ceratopicanol ( 1 ). 
20 Citations
Natural product syntheses via carbonylative cyclizations.
5.24 The Pauson–Khand Reaction
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