Total Synthesis and Stereochemical Assignment of (±)-Sorbiterrin A

@article{Qi2014TotalSA,
  title={Total Synthesis and Stereochemical Assignment of (±)-Sorbiterrin A},
  author={Chao Qi and Tian Qin and D. Suzuki and J. Porco},
  journal={Journal of the American Chemical Society},
  year={2014},
  volume={136},
  pages={3374 - 3377}
}
A concise, biomimetic approach to sorbiterrin A has been developed employing consecutive Michael additions of a 4-hydroxypyrone to a sorbicillinol derivative and silver nanoparticle-mediated bridged aldol/dehydration to construct the [3.3.1] ring system. The relative stereochemistry of sorbiterrin A was unambiguously confirmed by X-ray crystallographic analysis. 
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