Tl2Te and its relationship with Tl5Te3.

  title={Tl2Te and its relationship with Tl5Te3.},
  author={Radovan {\vC}ern{\'y} and Jean-Marc Joubert and Yaroslav Filinchuk and Yves Feutelais},
  journal={Acta crystallographica. Section C, Crystal structure communications},
  volume={58 Pt 5},
The crystal structure of Tl(2)Te, dithallium telluride, has been determined by single-crystal X-ray diffraction. The analysis of the structure shows that this compound is the first known representative of a new crystal structure type. The structural relationship with the related Tl(5)Te(3) phase is discussed. 

Figures and Tables from this paper

Structures and properties of the ternary thallium chalcogenides Tl2MQ3 (M = Zr, Hf; Q = S, Se).
New compounds of the formula Tl(2)MQ(3), with M = Zr and Hf and Q = S and Se, are synthesized, and their crystallographic features, electronic structures and electrical conductivity are studied.
Syntheses, crystal structures and thermoelectric properties of two new thallium tellurides: Tl4ZrTe4 and Tl4HfTe4
Three new isostructural tellurides Tl4MTe4 with M = Zr and Hf were prepared from the constituent elements. Single crystal X-ray diffraction data analyses showed that these compounds belong to a new
New thallium neodymium tellurides
The phase equilibria in the composition region Tl2Te-Tl2Te3-Nd2Te3-NdTe of the Tl-Nd-Te system have been studied by differential thermal analysis and x-ray diffraction, and the 500-K section of its
New quaternary chalcogenides, Tl18Pb2M7Q25 (M = Ti, Zr, and Hf; Q = S and Se): crystal structure, electronic structure, and electrical transport properties.
New quaternary chalcogenides of the general formula Tl(18)Pb(2)M(7)Q(25) (M = Ti, Zr and Hf, Q = S, Se) are synthesized and studied their crystal and electronic structures.
Ternary system Tl-Er-Te was experimentally investigated in the Tl2Te-Tl5Te3-Tl9ErTe6 compositions area by methods of differential thermal analysis, powder X-ray diffraction technique and
Crystal structures and thermoelectric properties of the series Tl(10-x)La(x)Te6 with 0.2 ≤ x ≤ 1.15.
The tellurides Tl(10-x)La(x)Te( 6) were synthesized from the elements in stoichiometric ratios at 873 K, followed by slow cooling, and the highest thermoelectric figure-of-merit determined thus far is 0.21 at 581 K for cold-pressed Tl (9)LaTe(6).
New Thallium Dysprosium Tellurides and Phase Equilibria in the System Tl2Te–Tl5Te3–Tl4DyTe3
Abstract The existence of the ternary compounds Tl 9 DyTe 6 and Tl 4 DyTe 3 was predicted and their synthesis was performed based on the analysis of structural features of Tl 5 Te 3 . It was shown
Phase equilibria in the Tl2Te-SnTe-Bi2Te3 system
Abstractphase equilibria in the Tl2Te-SnTe-Bi2Te3 system were studied by differential thermal analysis (DTA), X-ray powder diffraction, and microhardness measurements. Some polythermal sections and
Phase equilibria in the Tl-TlCl-Te system and thermodynamic properties of the compound Tl5Te2Cl
The Tl-Te-Cl system was studied in the Tl-TlCl-Te composition region by differential thermal analysis, X-ray powder diffraction, and emf and microhardness measurements. A series of polythermal


Phase diagram investigation and thermodynamic evaluation of the thallium-tellurium system
Differential scanning calorimetry and X-ray diffraction measurements led to conclude the existence of the phase T1 2 Te. From the obtained measurements and literature data, an
Kristallstruktur von Tl5Te3 und Tl2Te3
Crystallization of Te100−xTlx alloys (15≤x≤50) obtained by rapid cooling from the liquid state
The crystallization of foils of Te100−xTlx prepared by rapid cooling from the liquid state has been studied. In most cases the early stages of the amorphous‐crystalline transformation lead to a
Extinction within the limit of validity of the Darwin transfer equations. II. Refinement of extinction in spherical crystals of SrF2 and LiF
The extinction-correction formalisms derived in a previous article have been applied to two sets of diffraction data on spherical crystals. Application to the neutron data on SrF2, collected by
X-RED (Version 1.19) and IPDS Software (Version 2.92)
  • 1999
however (for it was the literal soul of the life of the Redeemer, John xv. io), is the peculiar token of fellowship with the Redeemer. That love to God (what is meant here is not God’s love to men)
The crystal structure of Tl5Te3and its relationship to the Cr5B3type
Assessment of the Te-Tl (tellurium-thallium) system
The optimized thermodynamic data for the Te- TI binary system have been obtained by the computer operated least squares method from measured data. The Gibbs energy of the liquid phase was modeled as
Über die Legierungen von Thallium und Tellur