Time-resolved IR studies of [Re(LL)(CO)4]+.


There is continuing interest in the excited-state behavior of transition metal-carbonyl complexes containing polypyridyl ligands.1-4 Their unique photophysical and photochemical properties are useful in a variety of areas, from biochemistry to materials science.5-15 Complexes of the form [M(bpy)(CO)4] (M is Cr, Mo, or W, and bpy is 2,2′-bipyridine) exhibit… (More)


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