Through-Bond and Chain-to-Chain Coupling. Two Pathways in Electron Tunneling through Liquid Alkanethiol Monolayers on Mercury Electrodes

Abstract

Formation, structure, and properties of alkanethiolate monolayers on micrometrically driven hanging mercury drop electrodes were investigated electrochemically. Alkanethiols with the chain length from C8 to C18 were shown to form densely packed (ca. 20.3 Å2/molecule for C12SH), perpendicularly oriented monolayers on mercury in a process involving two… (More)

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