Three-dimensional self-assembly of spherical block copolymer domains into V-shaped grooves.


The self-assembly of a spherical-morphology block copolymer into V-shaped grooves has been investigated. Although spherical morphology block copolymers typically form a bcc sphere array in bulk, the V groove promotes the formation of a well-ordered fcc close-packed sphere array with the (111) planes of the array parallel to the groove walls. The sphere size… (More)


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