Thiosulfate metal complexes

@article{Trachevskii2008ThiosulfateMC,
  title={Thiosulfate metal complexes},
  author={Volodymyr Trachevskii and S. V. Zimina and E. P. Rodina},
  journal={Russian Journal of Coordination Chemistry},
  year={2008},
  volume={34},
  pages={664-669}
}
The electronic structure of the thiosulfate ions was determined, which made it possible to predict and confirm experimentally for the first time the nature of their 33S NMR spectra containing two signals of functionally different sulfur atoms. The results of NMR study on different nuclei and the EPR data indicated that the thiosulfate ions as bifunctional ligands enter the coordination sphere of metals with different nature in accordance with the principle of hard and soft acids and bases. The… 
Syntheses and Structures of the First Lanthanide–Thiosulfate Complexes and the Subsequent Formation of Mixed Thiosulfate–Sulfite Compounds
The first rare-earth (RE) thiosulfate complexes, RE(S2O3)69–, have been crystallized via room-temperature reactions and structurally characterized through single-crystal X-ray diffraction. The inco...
Derivatives of cysteine related to the thiosulfate metabolism of sulfur bacteria by the multi-enzyme complex "Sox"-studied by B3LYP-PCM and G3X(MP2) calculations.
TLDR
The structures and thermodynamic properties of more than 60 related derivatives of cysteine (CysH) are investigated by high-level quantum chemical calculations both in the gas phase and in a polarizable continuum using the PCM method to simulate an aqueous solution.
Effects of Thiosulfate on the Adsorption of Arsenate on Hematite With a View to Phytoextraction
A study was carried out to evaluate how the adsorption process of arsenate on hematite is influenced by the presence of thiosulfate ion. The competition in sorption between the two anions was
Thiosulfate leaching of natural Acanthite ore in copper-ammonia-ammonium sulfate medium
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