Thiolate-Bound Thulium Compounds : Synthesis , Structure , and NIR Emission

@inproceedings{Banerjee2008ThiolateBoundTC,
  title={Thiolate-Bound Thulium Compounds : Synthesis , Structure , and NIR Emission},
  author={Santanu Banerjee and Gangadharan Ajith Kumar and Thomas J. Emge and Richard E Riman and John G Brennan},
  year={2008}
}
Molecular (DME)2Tm(SC6F5)3 and tetrametallic (DME)4(μ2-SPh)8Tm4(SPh)4 have been isolated in high yield and characterized by conventional methods. The fluorinated thiolate has an eight-coordinate Tm(III) ion bound to three sulfur atoms from the thiolates, four oxygen donors from the THF ligands, and a relatively weak dative Tm-F interaction with a 2.842(3… CONTINUE READING