Thermoreversible high-temperature gelation of an ionic liquid with poly(benzyl methacrylate-b-methyl methacrylate-b-benzyl methacrylate) triblock copolymer

@article{Kitazawa2012ThermoreversibleHG,
  title={Thermoreversible high-temperature gelation of an ionic liquid with poly(benzyl methacrylate-b-methyl methacrylate-b-benzyl methacrylate) triblock copolymer},
  author={Yuzo Kitazawa and T. Ueki and Kazuyuki Niitsuma and S. Imaizumi and T. Lodge and Masayoshi Watanabe},
  journal={Soft Matter},
  year={2012},
  volume={8},
  pages={8067-8074}
}
In this paper, we describe a novel thermosensitive triblock copolymer in an ionic liquid (IL) that shows a low-temperature-sol–high-temperature-gel transition. A well-defined ABA triblock copolymer consisting of poly(benzyl methacrylate) as the terminal A blocks and poly(methyl methacrylate) as the middle B block (P(BnMA-b-MMA-b-BnMA), BMB) was successfully synthesized using atom transfer radical polymerization (ATRP) from a bifunctional initiator. The number-average molecular weights of the… Expand
Photoreversible gelation of a triblock copolymer in an ionic liquid.
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