Thermodynamics and the structural aspects of the ternary complexes of Am(III), Cm(III) and Eu(III) with Ox and EDTA + Ox.


The stability constants and the associated thermodynamic parameters of formation of the binary and the ternary complexes of Am(3+), Cm(3+) and Eu(3+) were determined by a solvent extraction to measure the variation in the distribution coefficient with temperature (0-60 degrees C) for aqueous solutions of I = 6.60 m (NaClO(4)). The formation of ternary… (More)