Thermodynamic Properties of Aqueous Sodium Chloride Solutions
@article{Pitzer1984ThermodynamicPO, title={Thermodynamic Properties of Aqueous Sodium Chloride Solutions}, author={Kenneth S. Pitzer and J. Christopher Peiper and Richard H. Busey}, journal={Journal of Physical and Chemical Reference Data}, year={1984}, volume={13}, pages={1-102} }
Experimental measurements of the osmotic and activity coefficients, the enthalpy, and the heat capacity were used to derive a semiempirical equation for the thermodynamic properties of NaCl(aq) at constant pressure. This equation may be combined with results contained in the previous paper on the volumetric properties to yield a complete equation of state valid in the region 273 K≤T≤573 K, saturation pressure ≤P≤1 kbar, 0≤m≤6.0 mol kg−1. It is shown that this equation may be extrapolated to…
648 Citations
Thermodynamics of the aqueous sodium and magnesium bromide system at the temperatures 273.15 K and 298.15 K
- Chemistry
- 1996
Re-Evaluation of the Thermodynamic Activity Quantities in Aqueous Sodium and Potassium Chloride Solutions at 25 °C
- Chemistry
- 2009
The Huckel equation is used to correlate the experimental activities of dilute NaCl and KCl solutions up to a molality of about 1.0 mol·kg−1. The two parameters of this equation are dependent on the…
Modeling the thermodynamic properties of sodium chloride in steam through extended corresponding states
- Chemistry
- 1988
Recent precise data on anomalous behavior of apparent molar properties of electrolyte solutions in near-critical steam have raised important questions as to how the thermodynamic properties of these…
Mean Activity Coefficients and Osmotic Coefficients in Dilute Aqueous Sodium or Potassium Chloride Solutions at Temperatures from (0 to 70) °C
- Chemistry
- 2016
Two-parameter Huckel equations have been determined for the activity coefficient of the salt and for the osmotic coefficient of water in aqueous NaCl or KCl solutions at 0 °C from the highly accurate…
Prediction of thermodynamic properties of aqueous electrolyte solutions using equation of state
- Chemistry
- 2017
In this study, a predictive model is presented for estimation of second order thermodynamic properties of electrolyte solutions. In order to provide a comprehensive understanding, the capability of…
The density model for estimation of thermodynamic parameters of reactions at high temperatures and pressures
- Chemistry
- 1991
Traceable Thermodynamic Quantities for Dilute Aqueous Sodium Chloride Solutions at Temperatures from (0 to 80) °C. Part 1. Activity Coefficient, Osmotic Coefficient, and the Quantities Associated with the Partial Molar Enthalpy
- Chemistry
- 2017
We present fully traceable two-parameter Huckel equations (with parameters B and b1) for the activity coefficient of sodium chloride and for the osmotic coefficient of water in aqueous NaCl solutions…
Prediction of Electrolyte Solubilities from Minimal Thermodynamic Information
- Chemistry
- 2001
Summary. A method is proposed that permits the proper extrapolation of thermodynamic quantities represented by the Pitzer equations from 25°C to other temperatures. The new method, which assumes…
Determination of water activity, osmotic coefficients, activity coefficients, solubility and excess Gibbs free energies of NaCl-sucrose-H2O mixture at 298.15 K
- ChemistryJournal of Molecular Liquids
- 2019
References
SHOWING 1-4 OF 4 REFERENCES
Chemical Thermodynamic Studies of Aqueous Trace Components in Light Water Reactors at High Temperature and Pressure
- Electric Power Research Institute Report,
- 1978
Chapter 7 in "Activity Coefficients in Electrolyte Solutions
- 1979
Mesmer (submitted for publication)
- J. Chem. Thermooyn
- 1978
O=luy..w Surv"y, Open-file Rc:poTL 78-':;49
- Ir:. U.S. Geological Survey, Bulletin 1421-A,
- 1978