Thermo-, photo-, and chemo-responsive shape-memory properties from photo-cross-linked metallo-supramolecular polymers.


Films exhibiting multiresponsive shape-memory properties have been accessed using covalently cross-linked metallo-supramolecular polymers. Low molecular weight poly(butadiene) was end-capped with 4-oxy-2,6-bis(N-methylbenzimidazolyl)pyridine (-OMebip) ligands that upon addition of metal salts spontaneously formed high molecular weight metallo-supramolecular… (More)
DOI: 10.1021/ja205332w

11 Figures and Tables


  • Presentations referencing similar topics